PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 Decal & Paint Stripper 80577 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Decal & Paint Stripper Item No.: 80577 Part No.: 161DA Product Type: Aerosol, Paint Remover 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % METHYLENE CHLORIDE* 75-09-2 10-15 ISOBUTANE 75-28-5 5-15 ISOPROPYL ALCOHOL 67-63-0 5-15 PROPANE 74-98-6 5-15 ETHYL BENZENE* 100-41-4 1-5 ETHANOL, 2-AMINO- 141-43-5 1-5 Fatty acid diethanolamide 68604-35-3 1-5 STODDARD SOLVENT 8052-41-3 1-5 XYLENES* 1330-20-7 1-5 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) METHYLENE CHLORIDE 50 ppm TWA 500 ppm TWA None 174 mg/m3 1000ppm ceiling ISOPROPYL ALCOHOL 400 ppm TWA 400 ppm TWA None 983 mg/m3 980 mg/m3 PROPANE Asphyxiant 1000 ppm None 1800 mg/m3 ETHYL BENZENE 100 ppm 100 ppm None 434 mg/m3 435 mg/m3 ETHANOL, 2-AMINO- 3 ppm 3 ppm None 7.5 mg/m3 8 mg.m3 STODDARD SOLVENT 100 ppm 100 ppm None 525 mg/m3 525 mg/m3 XYLENES 100 ppm TWA 100 ppm TWA None 434 mg/m3 435 mg/m3 Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) METHYLENE CHLORIDE None 300ppm 5minutes in 3 hours PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: Decal & Paint Stripper Item No.: 80577 2. COMPOSITION, INFORMATION ON INGREDIENTS (continued) ISOPROPYL ALCOHOL 500 ppm 500 ppm 1230 mg/m3 1225 mg/m3 ETHYL BENZENE 125 ppm 125 ppm 543 mg/m3 545 mg/m3 ETHANOL, 2-AMINO- 6 ppm 6 ppm 15 mg/m3 15 mg/m3 XYLENES 150 ppm 150 ppm 651 mg/m3 655 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: Eye and skin irritant. Moderately toxic by inhalation or ingestion. Primary Routes of Entry: Inhalation, ingestion, skin contact Signs and symptoms of Exposure: Headache, nausea, dizziness. Narcosis at high concentrations. Aqua Ammonia in this product contains vapors and mists that are extremely corrosive to the nose, throat and mucous membranes. Bronchitis, pulmonary edema and chemical pneumonitis may occur. Irritation, coughing, chest pain and difficulty in breathing may occur wiht brief exposure while prolonged exposure may result in more severe irritation & tissue damage. Existing Conditions Aggravated by Exposure: Cardiovascular problems may be aggravated by overexposure to methylene chloride. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA METHYLENE CHLORIDE AC3 CNS IRR LIV YES 2B NO ISOBUTANE CAR CNS LUN NO NO NO ISOPROPYL ALCOHOL ALG CNS IRR NO N/A NO PROPANE CAR CNS IRR NO NO NO ETHYL BENZENE CNS IRR NO NO NO ETHANOL, 2-AMINO- IRR KID LIV NO NO NO Fatty acid diethanolamide No Data NO NO NO STODDARD SOLVENT CNS IRR NO NO NO XYLENES AC4 CAR CNS IRR KID LIV NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC3 ACGIH animal carcinogen. AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CAR Cardiac PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: Decal & Paint Stripper Item No.: 80577 3. HAZARDS IDENTIFICATION (continued) CNS Central nervous system IRR Irritant KID Kidney LIV Liver LUN Lung 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: Below -20°F (Propellant) Method: Tag Open Cup Recommended Extinguishing Agents: Carbon dioxide, dry chemical, water fog Hazardous Products formed by Fire or Thermal Decomp Carbon Monoxide, Carbon Dioxide, Hydrogen Chloride, Phosgene Gas. Unusual Fire or Explosion Hazards: Heated cans may burst Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Maintain adequate ventilation. Remove sources of ignition. Soak up in an inert absorbent. Store in a closed container disposal. 7. HANDLING AND STORAGE Safe Storage: Keep away from heat, spark, or open flame. Store below 120°F. Keep at room temperature as exposure to direct sunlight or heat may cause bursting. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged breathing of vapors. Keep away from eyes. Avoid prolonged skin contact. Do not use near sources of ignition. Do not puncture. Do not spray near fire or open PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: Decal & Paint Stripper Item No.: 80577 7. HANDLING AND STORAGE (continued) flame 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear liquid Odor: Mild Boiling Point: Propellant below 0 Degrees F pH: Does not apply Solubility in Water: Insoluble Specific Gravity Not Available Volatile Organic Compound (EPA Method 24) 93 % Vapor Pressure: Not available Vapor Density: Heavier than air Evaporation Rate (Ether = 1) More than 1 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Solvent may react with strong oxidizers and active metals. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: Decal & Paint Stripper Item No.: 80577 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. Do not incinerate cans still under pressure. EPA Hazardous Waste Number D001/F002 - Hazardous waste per 40CFR 261.21 and 261.31/Methylene Chloride 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Aerosols, flammable, n.o.s. containing substances in Division 6.1, Packing Group III Class or Division: Class 2.1 Subsidiary Risk 6.1 UN or ID Number: UN 1950 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Dichloromethane 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 3 Fire Hazard: 4 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 3 Flammability Hazard: 4 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Jean B. Tobbe Title: Environmental Health & Safety Specialist Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: Decal & Paint Stripper Item No.: 80577 16. OTHER INFORMATION (continued) (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0004